Acrylonitrile don NBR,
Acrylonitrile Don Nitrile Rubber,
Nitrile (wanda aka fi sani da buna-N roba ko perbunan) shine mafi yawan amfani da elastomer a cikin masana'antar hatimi.Nitrile copolymer ne na monomers guda biyu: acrylonitrile (ACN) da butadiene.Abubuwan da ke cikin waɗannan mahadi na roba an ƙaddara su ta hanyar abun ciki na ACN, wanda ya kasu kashi uku:
Babban nitrile> 45% abun ciki na ACN,
Matsakaicin nitrile 30-45% abun ciki na ACN,
Ƙananan nitrile <30% abun ciki na ACN.
Mafi girman abun ciki na ACN, mafi kyawun juriya ga mai.Ƙarƙashin abun ciki na ACN shine mafi kyawun sassauci a aikace-aikacen ƙananan zafin jiki.Matsakaicin nitrile shine, saboda haka, mafi yadu ƙayyadadde saboda kyakkyawan ma'aunin sa gaba ɗaya a yawancin aikace-aikace.Yawanci, ana iya haɗa nitriles don yin aiki akan kewayon zafin jiki na -35 ° C zuwa + 120 ° C kuma sun fi yawancin elastomers dangane da saitin matsawa, tsagewa da juriya.
Sunan samfur | Acrylonitrile |
Wani Suna | 2-Propenenitrile, Acrylonitrile |
Tsarin kwayoyin halitta | Saukewa: C3H3N |
CAS No | 107-13-1 |
EINECS No | 203-466-5 |
UN NO | 1093 |
Hs Code | Farashin 292610000 |
Nauyin kwayoyin halitta | 53.1 g/mol |
Yawan yawa | 0.81 g/cm3 a 25 ℃ |
Wurin tafasa | 77.3 ℃ |
Wurin narkewa | -82 ℃ |
Matsin tururi | 100 torr a 23 ℃ |
Solubility Solubility a isopropanol, ethanol, ether, acetone, da kuma benzene Conversion factor | 1 ppm = 2.17 mg/m3 a 25 ℃ |
Tsafta | 99.5% |
Bayyanar | Ruwa mai haske mara launi |
Aikace-aikace | Ana amfani dashi a cikin kera na polyacrylonitrile, roba nitrile, dyes, resins na roba. |
Gwaji | Abu | Daidaitaccen Sakamakon |
Bayyanar | Ruwa mai haske mara launi | |
Launi APHA PT-Co :≤ | 5 | 5 |
acidity (acetic acid) mg/kg ≤ | 20 | 5 |
PH (5% maganin ruwa) | 6.0-8.0 | 6.8 |
Darajar titration (5% maganin ruwa) ≤ | 2 | 0.1 |
Ruwa | 0.2-0.45 | 0.37 |
Aldehydes darajar (acetaldehyde) (mg/kg) ≤ | 30 | 1 |
Darajar Cyanogens (HCN) ≤ | 5 | 2 |
Peroxide (hydrogen peroxide) (mg/kg) ≤ | 0.2 | 0.16 |
Fe (mg/kg) ≤ | 0.1 | 0.02 |
Ku (mg/kg) ≤ | 0.1 | 0.01 |
Acrolein (mg/kg) ≤ | 10 | 2 |
Acetone na iya haifar da raguwa a cikin jini | 80 | 8 |
Acetonitrile (mg/kg) ≤ | 150 | 5 |
Propionitrile (mg/kg) ≤ | 100 | 2 |
Oxazole (mg/kg) ≤ | 200 | 7 |
Methylacrylonitrile (mg/kg) ≤ | 300 | 62 |
Abun ciki na Acrylonitrile (mg/kg) ≥ | 99.5 | 99.7 |
Kewayon tafasa (a 0.10133MPa) ℃ | 74.5-79.0 | 75.8-77.1 |
Polymerization inhibitor (mg/kg) | 35-45 | 38 |
Kammalawa | Sakamakon ya dace da tsayawar kasuwanci |
Ana samar da Acrylonitrile ta kasuwanci ta hanyar propylene ammoxidation, wanda propylene, ammonia, da iska ke amsawa ta hanyar mai kara kuzari a cikin gado mai ruwa.Ana amfani da Acrylonitrile da farko azaman co-monomer wajen samar da filaye na acrylic da modacrylic.Abubuwan da ake amfani da su sun haɗa da samar da robobi, rufin sama, nitrile elastomers, resins na shinge, da adhesives.Hakanan tsaka-tsakin sinadarai ne a cikin haɗakar antioxidants daban-daban, magunguna, rini, da aiki mai aiki.
1. Acrylonitrile sanya daga polyacrylonitrile fiber, wato acrylic fiber.
2. Acrylonitrile da butadiene za a iya copolymerized don samar da nitrile roba.
3. Acrylonitrile, butadiene, styrene copolymerized don shirya guduro ABS.
4. Acrylonitrile hydrolysis na iya samar da acrylamide, acrylic acid da esters.